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The Synthesis, Characterization og reaktivitet av en serie av Ruthenium
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The Synthesis, Characterization og reaktivitet av en serie av Ruthenium

Article DOI: 10.3791/52689-v • 10:51 min • April 10th, 2015
April 10th, 2015 •
1, 1, 1
1Department of Chemistry, Imperial College London

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Ruthenium fosfin-komplekser er mye brukt for homogene katalytiske reaksjoner som for eksempel hydrogeneringer. Syntesen av en serie nye ruteniumkomplekser tridentat som bærer N -triphos ligand N (CH2 PPh 2) 3 er rapportert. I tillegg er den støkiometriske reaksjon av en dihydrid Ru- N -triphos kompleks med levulinsyre beskrevet.

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Kjemi ligand -fosfin koordinasjon kompleks katalyse ruthenium biomasse levulinsyre
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