Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst

The overall goal of this procedure is to produce well-defined polymethyl methacrylate using perylene as a visible light photocatalyst for atom transfer radical polymerization. The overall goal of this procedure is to produce well-defined polymethyl methacrylate using perylene as an organic photocatalyst for atom transfer radical polymerization. This method can help answer key questions in the field of organic catalysis and photoredox catalysis such as, can we replace transition metal complexes with organic dyes such as perylene?

The main advantage of this technique is that the metal catalyst commonly used in atom transfer radical polymerization can be replaced with perylene, a common organic dye. Visual demonstration of this method is critical to ensure reproducibility among research groups, as the exact reaction setup can have a substantial impact on the outcome of the experiment. Prepare all reagents as described in the text protocol, and allow them to come to room temperature.