A subscription to JoVE is required to view this content. Sign in or start your free trial.

Method Article

Casting Protocols for the Production of Open Cell Aluminum Foams by the Replication Technique and the Effect on Porosity

14.5K views

⸱

DOI:

10.3791/52268

⸱

December 11th, 2014

 ,  ,  , 

In This Article

Erratum Notice

Important: There has been an erratum issued for this article. View Erratum Notice

Summary

Replication is one of the processing techniques used for the production of porous metal sponges. In this paper one implementation of the method for the production of open celled porous aluminum is shown in detail.

Abstract

Metal foams are interesting materials from both a fundamental understanding and practical applications point of view. Uses have been proposed, and in many cases validated experimentally, for light weight or impact energy absorbing structures, as high surface area heat exchangers or electrodes, as implants to the body, and many more. Although great progress has been made in understanding their structure-properties relationships, the large number of different processing techniques, each producing material with different characteristics and structure, means that understanding of the individual effects of all aspects of structure is not complete. The replication process, where molten metal is infiltrated between grains of a removable preform material, allows a markedly high degree of control and has been used to good effect to elucidate some of these relationships. Nevertheless, the process has many steps that are dependent on individual “know-how”, and this paper aims to provide a detailed description of all stages of one embodiment of this processing method, using materials and equipment that would be relatively easy to set up in a research environment. The goal of this protocol and its variants is to produce metal foams in an effective and simple way, giving the possibility to tailor the outcome of the samples by modifying certain steps within the process. By following this, open cell aluminum foams with pore sizes of 1–2.36 mm diameter and 61% to 77% porosity can be obtained.

Introduction

Metal foams have attracted a large amount of interest and research effort in recent years as shown by the large body of work cited in wide ranging review articles such as Banhart1, Conde et al.2 or more recently Goodall and Mortensen3. Among the methods used for production of the material, the replication process is distinguished by its experimental simplicity and the degree of control over the final foam structure that can be offered. It should be noted that although in the literature such materials are often described as foams (and are here) as they are not produced by bubbles of gas within a liquid they are more appropriate....

Access restricted. Please log in or start a trial to view this content.

Protocol

NOTE: The instructions below are for Protocol A (Figure 1). Modifications for Protocol B, C, and D are listed as well.

1. Aluminum Bar Preparation

  1. Place a large piece (500 g – 1 kg) of commercial purity aluminum ingot into a crucible.
  2. Place the crucible in a furnace at 800 °C for about 1 hr, until molten.
  3. Take the crucible out of the furnace and pour the molten aluminum into a cylindrical mold that is 50 mm in diameter, slightly smaller than the final diameter of the chamber to be used for infiltration (51 mm) giving a gap of about ½ mm.
  4. Wait 1 hr for the bar to cool....

Access restricted. Please log in or start a trial to view this content.

Results

In Figure 4 the morphology of the NaCl grains can be seen (angular and spherical), for illustrative purposes. The foams obtained with Protocol A were made using angular shaped grains and the rest were made with the spherical grains. It was found that the use of different shape NaCl grains had no observed effect on the porosity obtained in the samples.

From the results we can determine that samples a, b, and c (made with Protocol A), are on average 63% porous (Figure 5<.......

Access restricted. Please log in or start a trial to view this content.

Discussion

The basic method described here has been used in different forms by other researchers. Some of the key variants that allow foams of different types to be created are discussed. In characterizing these foams we have measured the porosity, as this is a quick and easy assessment to make, but characterization of other structural characteristics, such as pore size, specific surface area or strut thickness might be required to obtain a full understanding of foam characteristics for different applications. In practice, for prod.......

Access restricted. Please log in or start a trial to view this content.

Disclosures

The authors declare that they have no competing financial interests.

Acknowledgements

The corresponding author would like to acknowledge the Mexican Government’s National Council of Science and Technology CONACYT for provision of a scholarship.

....

Access restricted. Please log in or start a trial to view this content.

Materials

List of materials used in this article
NameCompanyCatalog NumberComments
SaltHydrosoftGranular Salt 25 kg 855754http://www.travisperkins.co.uk/p/hydrosoft-granular-salt-25kg/855754/3893446
AluminumWilliam RowlandAluminum Ingots 99.87% pure 25 kg drumhttp://www.william-rowland.com/products/high-purity-metals#product-id-1
CrucibleMorgan Advance MaterialsSyncarb Cruciblehttp://www.morganmms.com/crucibles-foundry-products/crucibles/syncarb/
FurnaceElite Thermal SystemsTLCF10/27-3216CP & 2116 O/Thttp://www.elitefurnaces.com/eng/products/furnaces/1200%20Top%20Loading%20Furnaces.php
Bar MoldThe University of SheffieldCustom MadeStainless Steel 304, 15 cm height, 5 cm inner diameter, 6 cm outer diameter
Band SawClarkeCBS45MD (6" x 4 1/2") 370W 060710025http://www.machinemart.co.uk/shop/product/details/cbs45md-41-2in-x-6in-metal-cutting-ban
SandpaperWickesSpecialist wet & dry sandpaper 501885http://www.wickes.co.uk/Specialist-Wet+Dry-Sandpaper-PK4/p/501885
SievesFisher ScientificFisherbrand test sieves 200 mm diamaterhttp://www.fisher.co.uk/product/brand_listing.php/F/Fisherbrand/Sieve
BalancePrecisaXB 6200Chttp://www.precisa.co.uk/precision_balances.php
Boron NitrideKennametal500 ml spray canhttp://www.kennametal.com/content/dam/kennametal/kennametal/common/Resources/Catalogs-Literature/Advanced%20Materials%20and%20Wear%20Components/B-13-03401_ceramic_powders
_brochure_EN.pdf
Infiltration Mold, Base and LidThe University of SheffieldCustom MadeStainless Steel 304, 15 cm height, 5.1 cm inner diameter, 6 cm outer diameter
Cylindrical MoldThe University of SheffieldCustom MadeLow carbon steel 1020, 15 cm height, 5 cm inner diameter, 6 cm outer diameter
Graphite GasketGee GraphiteGeegraf Stainless Steel Reinforced Graphite 1 mm thickhttp://www.geegraphite.com/steel_reinforced.html
MalletThor Hammer Co. Ltd.Round Solid Super Plastic Mallethttp://www.thorhammer.com/Mallets/Round/
WrenchKennedy Professional13 mm Ratchet Combination Wrench KEN5822166Khttps://www.cromwell.co.uk/KEN5822166K
NutsMatlockM8 Steel hex full nut galvanizedhttps://www.cromwell.co.uk/CTL6400068J
WashersMatlockM8 Form-A steel washer bzphttps://www.cromwell.co.uk/CTL6451208H
SS NutsMatlockM8 A2 st/st hex full nuthttps://www.cromwell.co.uk/CTL6423008F
SS WashersMatlockM8 A2 st/st Form-A washerhttps://www.cromwell.co.uk/CTL6464008H
Stainless Steel StuddingCromwellM8 x 1 Mtr A2 Stainless Steel Studding QFT6397080Khttps://www.cromwell.co.uk/QFT6397080K
ValvesEdwardsC33205000 SP16K, Nitrile Diaphragmhttps://www.edwardsvacuum.com/Products/View.aspx?sku=C33205000
Fitting CrossEdwardsC10512412 NW16 Cross Piece Aluminumhttps://www.edwardsvacuum.com/Products/C10512412/View.aspx
Fitting TEdwardsC10512411 NW16 T-Piece Aluminumhttps://www.edwardsvacuum.com/Products/C10512411/View.aspx
Vacuum PumpEdwardsA36310940 E2M18 200-230/380-415V, 3-ph, 50 Hzhttp://www.edwardsvacuum.com/Products/View.aspx?sku=A36310940
Dial GaugeEdwardsD35610000 CG16K, 0-1,040 mbarhttp://www.edwardsvacuum.com/Products/View.aspx?sku=D35610000
Argon GasBOCPureshield Argon Gashttp://www.boconline.co.uk/en/products-and-supply/industrial-gases/inert-gases/pureshield-argon/pureshield-argon.html
Stainless Steel HoseBOCStainless Steel Hosehttp://www.boconline.co.uk/en/products-and-supply/speciality-equipment/hoses-and-pigtails/index.html
RegulatorBOCHP 1500 Series Regulatorhttp://www.boconline.co.uk/en/products-and-supply/speciality-equipment/regulators/single-stage-regulators/hp1500-series/hp1500-series.html
Copper BlockWilliam RowlandCopper Ingot 25 kghttp://www.william-rowland.com/products/high-purity-metals#product-id-18
ViseRecordT84-34 H/Duty Eng Vice 4 1/2" Jaws REC5658326Khttps://www.cromwell.co.uk/REC5658326K
BeakerFisher Scientific11567402 - Beaker, squat form, with graduations and spout 800 mlhttps://webshop.fishersci.com/insight2_uk/getProduct.do;jsessionid=16D5812
D71B8CB37B475E94281E2BEA
5.ukhigjavappp11?productCode=11567402&resultSet
Position=0
Stirring Hot PlateCorningCorning stirring hot plate Model 6798-420dhttp://www.corning.com/lifesciences/us_canada/en/technical_resources/product_guid/shp/shp.aspx
[header]
Stir BarFisher Scientific11848862 - PTFE Stir bar + Ring 25x6 mmhttps://webshop.fishersci.com/insight2_uk/getProduct.do;jsessionid=16D5812
D71B8CB37B475E94281E2BEA
5.ukhigjavappp11?productCode=11848862&resultSet
Position=0
Air dryerV05V05 Max Air Turbo Dryer DR-120-GBhttp://reviews.boots.com/2111-en_gb/1120627/v05-v05-max-air-turbo-hair-dryer-dr-120-gb-reviews/reviews.htm
Ceramic SheetMorgan Advance MaterialsKaowool Blanket 2 mm thickhttp://www.morganthermalceramics.com/downloads/datasheets?f[0]=field_type%3A84
Vibrating TablePeveril MachineryPevco Vibrating Table 1.25 m x 0.625 m x 0.6 mhttps://peverilmachinery.co.uk/equipment/vibrating-tables

References

  1. Banhart, J. Manufacture, characterisation and application of cellular metals and metal foams. Progress in Materials Science. 46, 559-632 (2000).
  2. Conde, Y., Despois, J. -F., Goodall, R., Marmottant, A., Salvo, L., San Marchi, C., Mortensen, A. Replicat....

Access restricted. Please log in or start a trial to view this content.

Reprints and Permissions

Erratum


Formal Correction: Erratum: Casting Protocols for the Production of Open Cell Aluminum Foams by the Replication Technique and the Effect on Porosity
Posted by JoVE Editors on 8/03/2015. Citeable Link.

A journal reference was corrected in the publication of Casting Protocols for the Production of Open Cell Aluminum Foams by the Replication Technique and the Effect on Porosity. Reference 21 and 22 were originally merged together as one reference. They have been separated into references 21 and 22 in the article. The reference numbers have been updated in the article to reflect this additional reference citation. It has been updated from:

  1. LeMay, J.D., Hopper, R.W., Hrubesh, L.W., & Pekala, R.W. Low-Density Microcellular Materials. Materials Research Society Bulletin. 15 (12), 19–20 (1990).Seliger, H., & Deuther U. Die Herstellung von Schaum- und Zellaluminium. Feiburger Forschungshefte. 103–129 (1965).

to:

  1. LeMay, J.D., Hopper, R.W., Hrubesh, L.W., & Pekala, R.W. Low-Density Microcellular Materials. Materials Research Society Bulletin. 15 (12), 19–20 (1990).
  2. Seliger, H., & Deuther U. Die Herstellung von Schaum- und Zellaluminium. Feiburger Forschungshefte. 103–129 (1965).

Explore More Articles

Aluminum Foam ProductionSodium Chloride InfiltrationOpen Cell FoamsPorosity ControlMold PreparationArgon Gas PressureFurnace HeatingSample ExtractionWater Bath Leaching