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Chapter 9

Enlace químico: Conceptos básicos

Chapter 9

Chemical Bonding: Basic Concepts

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Chemical bonding theories were pioneered by American chemist Gilbert N. Lewis. He developed a model called the Lewis model to explain the type and …
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Chemical bonds are complex interactions between two or more atoms or ions, which reduce the potential energy of the molecule. Gilbert N. Lewis developed a …
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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence …
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Lattice Energy  An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a …
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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure …
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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual …
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Whether a bond is nonpolar or polar covalent is determined by a property of the bonding atoms called electronegativity.  Electronegativity values of …
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Bond Polarity The absolute value of the difference in electronegativity (ΔEN) of two bonded atoms provides a rough measure of the polarity to be …
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To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined: Determine the …
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The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O …
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In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to …
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Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories: …
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Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, …
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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the …
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Amphiphilic molecules equipped with a reactive, carbon-rich “oligoyne” segment consisting of conjugated carbon-carbon triple bonds self-assemble into …
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We present a pump-probe method for preparing vibrational coherences in polyatomic radical cations and probing their ultrafast dynamics. By shifting the …