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Palladium N-Heterocyclic Carbene Complexes

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Article DOI: 10.3791/54932-v 19:59 min July 30th, 2017
July 30th, 2017



Detailed and generalized protocols are presented for the synthesis and subsequent purification of four palladium N-heterocyclic carbene complexes from benzimidazolium salts. The complexes were tested for catalytic activity in arylation and Suzuki-Miyaura reactions. For each reaction investigated, at least one of the four complexes successfully catalyzed the reaction.


Palladium N-Heterocyclic Carbene Complexes Synthesis Purification Benzimidazolium Salts Catalytic Activity Carbon-carbon Bond-forming Reactions Arylation Suzuki-Miyaura Cross-Coupling Protocol Demonstration
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