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Preparation and Reactivity of a Triphosphenium Bromide Salt

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)

Article DOI: 10.3791/55021
November 22nd, 2016


Summary November 22nd, 2016

The synthesis of a triphosphenium bromide salt is described and its use as a P+ transfer agent is outlined by reactions with an N-heterocyclic carbene and an anionic bisphosphine, yielding an NHC-stabilized P(I) cation and a P(I) containing zwitterion, respectively.


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