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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
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JoVE Journal Chemistry
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

DOI:
10.3791/54789-v

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10:42 min

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December 29, 2016

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, , ,
1Department of Chemistry,University of California, Berkeley, 2Fachbereich Chemie,Philipps-Universität Marburg and Wissenschaftliches Zentrum für Materialwissenschaften

Chapters

  • 00:05Title
  • 01:04Preparation of Solvents and Solutions
  • 02:08High-temperature Solid-state Reactions
  • 04:04In Situ Reduction and Solvothermal Reactions
  • 06:00Reactive Layering
  • 07:20Results: Synthesis and Characterization of Chalcogenidoplumbates
  • 09:28Conclusion

Summary

Automatic Translation

Automatic Translation

The synthesis of chalcogenidoplumbates(II,IV) via the in situ reduction of nominal "PbCh2" (Ch = Chalcogen) and via a solid-state reaction and subsequent solvothermal reactions is presented. Additionally, reactivities of plumbate(II) solutions are portrayed, which yield the heaviest-known CO homolog known to date: the µ-PbSe ligand.

Tags

Keywords: Solid-state SynthesisSolution-based ChemistryChalcogenidoplumbatesSemi-conducting PropertiesMetallateIron SolutionsAir/moisture/light ExclusionDry SolventsWilkinson’s CatalystLead SelenidePotassium Lead

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