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Photogeneration av N-hetrosyklisk Carbenes
 
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Photogeneration av N-hetrosyklisk Carbenes: programmet i Photoinduced Ring-åpning Metathesis polymerisering

Article doi: 10.3791/58539
November 29th, 2018

Summary November 29th, 2018

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Vi beskriver en protokoll for å photogenerate N-hetrosyklisk carbenes (NHCs) ved UV bestråling av en 2-isopropylthioxanthone/imidazolium tetraphenylborate salt system. Metoder for å karakterisere photoreleased NHC og belyse fotokjemisk mekanismen er foreslått. Protokollene for ring-åpning metathesis photopolymerization i løsningen og miniemulsion illustrerer potensialet i dette 2-komponent NHC photogenerating systemet.

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