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JoVE Journal Chemistry
Synthese van monodispers cilindrische nanodeeltjes via kristallisatie-gedreven zelf-assemblage van biologisch afbreekbaar blok copolymeren
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Synthese van monodispers cilindrische nanodeeltjes via kristallisatie-gedreven zelf-assemblage van biologisch afbreekbaar blok copolymeren

Article DOI: 10.3791/59772-v • 11:42 min • June 20th, 2019
June 20th, 2019 •
1, 1, 1, 1
1Department of Chemistry, University of Birmingham

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Kristallisatie-gedreven zelf-assemblage (CDSA) toont de unieke capaciteit om cilindrische nanostructures van smalle lengte distributies te fabriceren. De organocatalyzed ring-opening polymerisatie van Epsilon-caprolacton en de daaropvolgende keten uitbreidingen van methyl methylmethacrylaat en n, n-dimethyl acrylamide worden aangetoond. Een levende CDSA protocol dat produceert monodispers cilinders tot 500 nm in lengte is geschetst.

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Chemie kristallisatie-gedreven zelf-assemblage ring-opening polymerisatie omkeerbare toevoeging-fragmentatie keten overdracht polymerisatie afbreekbare polymeren
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