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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Chemistry
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JoVE Journal Chemistry
Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

DOI:
10.3791/60348-v

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07:36 min

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November 09, 2019

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, , ,
1LCC-CNRS,Université de Toulouse, CNRS, 2LISBP,Université de Toulouse, CNRS, INRA, INSA

Chapters

  • 00:05Title
  • 00:57Compound 2 Synthesis
  • 02:46Compound 3 Synthesis
  • 04:07Compound 4 Synthesis
  • 05:34Results: Representative 1H NMR Analyses of Compounds 1 – 4
  • 06:59Conclusion

Summary

Automatic Translation

Automatic Translation

CO2 transformations are conducted in a one-pot two-step procedure for the synthesis of complex molecules. The selective 4 e- reduction of CO2 with a hydroborane reductant affords a reactive and versatile bis(boryl)acetal intermediate which is subsequently involved in condensation reaction or carbene-mediated C-C coupling generation.

Tags

Keywords: CO2 TransformationsOne-pot Two-step StrategyCascade ReactionsCO2 ReductionIntermediate ReactivityCompound SynthesisGlove BoxGas HandlingNMR AnalysisIron Catalyst9-BBN26-diisopropylethylamineTetrahydrofuran

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