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JoVE Journal Chemistry
Versatile CO2 Transformations into Complex Products
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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Article DOI: 10.3791/60348-v • 07:36 min • November 9th, 2019
November 9th, 2019 •
*1,2, *1, 1, 1
1LCC-CNRS, Université de Toulouse, CNRS, 2LISBP, Université de Toulouse, CNRS, INRA, INSA
* These authors contributed equally

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Summary
Automatic Translation

CO2 transformations are conducted in a one-pot two-step procedure for the synthesis of complex molecules. The selective 4 e- reduction of CO2 with a hydroborane reductant affords a reactive and versatile bis(boryl)acetal intermediate which is subsequently involved in condensation reaction or carbene-mediated C-C coupling generation.

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CO2 Transformations Complex Products One-pot Two-step Strategy Electron Reduction Reactive Intermediate Cascade Reactions CO2 Reduction Carbon Compound Synthesis Reaction Mixture Preparation Glove Box Gas Handling Visual Demonstration NMR Tube BBN Hexamethyl Benzene Iron Catalyst Solution Deuterated Tetrahydrofuran
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