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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
 

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Article DOI: 10.3791/57916 08:12 min
August 16th, 2018

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Summary August 16th, 2018

A two step one-pot protocol for the umpolung of ketone enolates to enolonium species and addition of a nucleophile to the α-position is described. Nucleophiles include chloride, azide, azoles, allyl-silanes, and aromatic compounds.

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