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DOI: 10.3791/54513-v
Purnandhu Bose1, Pradip K. Sukul1, Omar M. Yaghi2,3,4, Kentaro Tashiro1
1International Center for Materials Nanoarchitectonics,National Institute for Materials Science, 2Department of Chemistry,University of California–Berkeley, 3Materials Sciences Division,Lawrence Berkeley National Laboratory, 4Kavli Energy NanoSciences Institute at Berkeley,University of California–Berkeley
This article presents a method for synthesizing water-soluble multimetallic peptidic arrays with a predetermined sequence of metal centers. The technique aims to address challenges in organic chemistry, particularly in creating unique multi-nuclei heteromeric complexes.
A potential general method for the synthesis of water-soluble multimetallic peptidic arrays containing a predetermined sequence of metal centers is presented.
The overall goal of this synthetic procedure is to provide a rational way to make multi-metallic species with a pre-determined sequence of metal centers. This method can help answer key questions in organic chemistry field, such as building a unique, multi-nuclei heteromeric complex against the issues of phase separation and multiple structured outcomes. The main advantage of this technique is it's wide applicability for diverse chemical structures due to the simplicity of it's principle.
Demonstrating the procedure will be Purnandhu Bose, apostle from my laboratory. To begin this procedure, add 135 milligrams of TG sieber resin and distir bar to a 10-milliliter, two-neck flask bearing a drain at the bottom equipped with a glass filter and a two-way stopcock. Connect a three-way stopcock and a glass stopper to the joints of the flask.
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