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基于熔环环辛烯单体的可解聚烯烃聚合物
JoVE Journal
Chemistry
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JoVE Journal Chemistry
Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
DOI:

08:12 min

December 16, 2022

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Chapters

  • 00:05Introduction
  • 00:50tCBCO Monomer Preparation
  • 01:38Photochemical Isomerization
  • 03:23Synthesis of Polymer Network PN1
  • 04:53Depolymerization of Linear Polymer (P1)
  • 05:41Results: Reaction Schemes for tCBCO Small Molecules and Polymer Synthesis, GPC Traces for Polymer, Depolymerization of tCBCO-Based Polymers, and Stress Vs. Strain Curves
  • 07:14Conclusion

Summary

Automatic Translation

在这里,我们描述了制备 反式环丁烷熔融环辛烯(tCBCO)的方案,它们的聚合以制备可解聚的烯属聚合物,以及这些聚合物在温和条件下的解聚。此外,还描述了基于该系统制备可解聚网络和刚性线性塑料压缩成型的协议。

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