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Journal / Chemistry / [(DPEPhos) (BCP) cu] PF6: en allmän och i stort…
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JoVE Journal Chemistry
[(DPEPhos) (BCP) cu] PF6
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[(DPEPhos) (BCP) cu] PF6: en allmän och i stort sett tillämplig kopparbaserad Photoredox Catalyst

Article DOI: 10.3791/59739-v • 09:12 min • May 21st, 2019
May 21st, 2019 •
1, 1, 1, 1,2, 1, 2, 1
1Laboratoire de Chimie Organique, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB), 2Laboratoire de Chimie Organique et Photochimie, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB)

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Detaljerade och allmänna protokoll presenteras för syntesen av [(DPEPhos) (BCP) cu] PF6, en allmän kopparbaserad photoredox katalysator, och för dess användning i syntetisk kemi för direkt arylering av C-H obligationer i (hetero) Arenes och radikal cyklisering av organiska halogenider.

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Kemi koppar katalys photoredox katalys synligt ljus radikala reaktioner C-H arylation radikal cyklisering natur produkter cyanamider ynamides luotonin A
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