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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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JoVE Journal Chemistry
Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

DOI:
10.3791/64978-v

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05:26 min

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February 10, 2023

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, ,
1Department of Chemistry,Ulsan National Institute of Science and Technology (UNIST)

Chapters

  • 00:04Introduction
  • 00:43Synthesis of Cubic HKUST‐1
  • 02:01Synthesis and Solvent‐Exchange of HKUST‐1@MOF‐5 Core‐Shell
  • 03:20Results: Computational Structure Models, Optical Microscope Images, and PXRD Patterns of HKUST‐1 and HKUST‐1@MOF‐5 Core‐Shell
  • 04:34Conclusion

Summary

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Automatic Translation

Here, we demonstrate a protocol for the two-step synthesis of single-crystalline core-shells using a non-isostructural metal-organic framework (MOF) pair, HKUST-1 and MOF-5, which have well-matched crystal lattices.

Tags

Keywords: Core-shell MOFsMetal-organic FrameworksSolvothermal ReactionHKUST-1MOF-5Lattice-matchedGas SeparationCatalytic ApplicationCopper Nitrate135-benzenetricarboxylic AcidZinc NitrateTerephthalic AcidNN-DiethylformamideDichloromethane

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