A subscription to JoVE is required to view this content. Sign in or start your free trial.
Chapters
- 00:05Title
- 02:33Microwave-assisted Dehydrogenative DA Reaction
- 04:16Palladium-catalyzed Cross-coupling Reaction
- 07:06Preparation of Dye Solution for Photophysical Studies
- 07:50Fluorescence Emission Spectroscopy
- 08:47Results: Synthesis and Photophysical Analysis of Functionalized Nephthalenes/Solvatochromic Fluorescent Dyes
- 11:10Conclusion
Mikrobølgeovn-assistert intramolekylære dehydrogenative Diels-Alder (DA) reaksjoner gir konsis tilgang til functionalized syklopenta [<em> B</em>] Naftalen byggeklosser. Nytten av denne metodikken er demonstrert av ett-trinns konvertering av dehydrogenative DA cycloadducts i romanen solvatochromic fluorescerende fargestoffer via Buchwald-Hartwig palladium-katalysert krysskopling reaksjoner.
