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Journal
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Chemistry
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元素镧在选择性 c-F 活化 Trifluoromethylated Benzofulvenes 中的应用提供各种 Difluoroalkenes 的访问
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JoVE Journal
Chemistry
Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
Please note that all translations are automatically generated.
Click here for the English version.
元素镧在选择性 c-F 活化 Trifluoromethylated Benzofulvenes 中的应用提供各种 Difluoroalkenes 的访问
DOI:
10.3791/57948-v
•
10:10 min
•
July 28, 2018
•
Tarun Kumar
2
,
Amira Ben Hassine
,
Agathe Martinez
,
Dominique Harakat
,
Sylviane Chevreux
,
Fabien Massicot
,
Marc Taillefer
,
Jean-Bernard Behr
,
Jean-Luc Vasse
,
Florian Jaroschik
2
1
Institut de Chimie Moléculaire de Reims UMR 7312
,
Université de Reims Champagne Ardenne
,
2
Institut Charles Gerhardt Montpellier UMR 5253
,
Ecole Nationale Supérieure de Chimie de Montpellier
Chapters
00:04
Title
00:32
Preparation of Reactants
03:47
Dysprosium-Mediated C-F Activation and Nitroalkene Addition
08:14
Results: Characterization of Difluoroalkene Products
09:47
Conclusion
Summary
Automatic Translation
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Automatic Translation
本协议描述了惰性气氛下元素镧的制备及其在含有 trifluoromethylated benzofulvenes 的选择性 C F 活化过程中的应用。
Tags
Lanthanides
C-F Activation
Trifluoromethylated Benzofulvenes
Difluoroalkenes
Organic Chemistry
Reduction Chemistry
Metal-organic Reactions
Dysprosium
Aluminum Chloride
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