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功能性降冰片烯的催化聚合插入一种简单高效的协议
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Chemistry
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JoVE Journal Chemistry
A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
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功能性降冰片烯的催化聚合插入一种简单高效的协议

DOI:
10.3791/54552-v

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09:08 min

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February 27, 2017

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, , , , ,
1Department of Chemistry,Université de Sherbrooke

Chapters

  • 00:05Title
  • 00:53Preparation of Poly(5-norbornene-2-carboxylic acid)
  • 03:51Preparation of PNBE(vinyl)
  • 06:01Preparation of PNBE(epoxy)
  • 07:40Epoxidation of PNBE(vinyl)
  • 08:42Conclusion

Summary

Automatic Translation

Automatic Translation

We describe the catalytic insertion polymerization of 5-norbornene-2-carboxylic acid and 5-vinyl-2-norbornene to form functional polymers with a very high glass transition temperature.

Tags

Keywords: Catalytic Insertion PolymerizationFunctional PolynorbornenesHigh Glass Transition TemperatureReactive Functional GroupsEpoxy GroupsAcid GroupsCatalytic Polymer SynthesisAcrylic AcidDCPDNBE Carboxylic AcidAllylpalladium(II)chloride DimerSilver Antimonate

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