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Syntese af hypervalente iodonium Alkynyl Triflater om anvendelse af Generering Cyanocarbenes
 
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Syntese af hypervalente iodonium Alkynyl Triflater om anvendelse af Generering Cyanocarbenes

Article doi: 10.3791/50886
September 8th, 2013

Summary September 8th, 2013

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Click here for the English version.

Heri beskrives syntese, isolation og reaktioner hypervalente iodonium alkynylgrupper triflater (HIATs) med azider at generere cyanocarbenes. Procedurerne kan indebære air-sensitive og kryogene teknikker, herunder kold filtrering under en inert atmosfære. Håndtering og sikkerheden af ​​de syntetiserede forbindelser vil også blive drøftet.

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