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Journal / Chemistry / Facile Preparazione di (2
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JoVE Journal Chemistry
Facile Preparazione di (2
Genetic Encoding of a Non-Canonical Amino Acid for the Generation of Antibody-Drug Conjugates Through a Fast Bioorthogonal Reaction
Journal (Chemistry)
Genetic Encoding of a Non-Canonical Amino Acid for the Generation of Antibody-Drug Conjugates Through a Fast Bioorthogonal Reaction
Optimizing the Genetic Incorporation of Chemical Probes into GPCRs for Photo-crosslinking Mapping and Bioorthogonal Chemistry in Live Mammalian Cells
Journal (Chemistry)
Optimizing the Genetic Incorporation of Chemical Probes into GPCRs for Photo-crosslinking Mapping and Bioorthogonal Chemistry in Live Mammalian Cells
 
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Facile Preparazione di (2

Article DOI: 10.3791/55766-v • 06:46 min • June 21st, 2017
June 21st, 2017 •
1, 1, 2, 1, 1, 1
1College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, 2Shijiazhuang Mechanized Infantry Academy

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Qui è descritta l'olefina catalizzata da rutenio di alchenici con deficit di elettroni con allile acetato. Utilizzando l'aminocarbonil come gruppo di guida, questo protocollo esterno senza ossidanti ha un'elevata efficienza e una buona stereo- e regioselettività, aprendo un nuovo percorso sintetico agli scheletri ( Z , E ) -butadiene.

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Chimica Numero 124 dienamide olefina allile acetato rutenio ossidante 1,3-butadiene catalisi
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