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镍/锌配合物介导的O-Carboxyanhydrides 的控制 Photoredox 环开聚合

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JoVE Journal Chemistry

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

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镍/锌配合物介导的O-Carboxyanhydrides 的控制 Photoredox 环开聚合

DOI:

10.3791/56654-v

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05:48 min

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November 21, 2017

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Quanyou Feng², Rong Tong

¹Center for Molecular Systems and Organic Devices, Institute of Optoelectronic Materials, Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials,Nanjing University of Posts and Telecommunications, ²Department of Chemical Engineering,Virginia Polytechnic Institute and State University

Chapters

00:05Title
00:45Photoredox Ring-Opening Polymerization of Phenyl O-Corboxyanhydride (L-1)
03:49Results: Characterization of Poly(phenyl O-Corboxyanhydride)(poly(L-1))
04:59Conclusion

Summary

Automatic Translation

介绍了由 Ni/锌配合物介导的受控 photoredox 环开放聚合的O-carboxyanhydrides 的协议。

Tags

Keywords: Controlled Photoredox Ring-opening Polymerization O-carboxyanhydrides Ni/zn Complexes Poly(alpha-hydroxy Acids)High Molecular Weight Polyesters Side Chain Functional Groups Anhydrous THF Bipy-nickel(COD)Zinc Bis(hmds)Benzyl Alcohol Iridium Catalyst L1 Monomer Blue LED Light Temperature Control

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